| Jornada 1 | 27-08-2006 | REAL MADRID | 0 | VILLARREAL | 0 |
| Jornada 2 | 10-09-2006 | VILLARREAL | 0 | RECREATIVO | 1 |
| Jornada 3 | 17-09-2006 | DEPORTIVO | 2 | VILLARREAL | 0 |
| Jornada 4 | 24-09-2006 | VILLARREAL | 3 | ZARAGOZA | 2 |
| Jornada 5 | 01-10-2006 | MALLORCA | 1 | VILLARREAL | 2 |
| Jornada 6 | 15-10-2006 | VILLARREAL | 0 | ESPANYOL | 0 |
| Jornada 7 | 22-10-2006 | VILLARREAL | 1 | LEVANTE | 1 |
| Jornada 8 | 29-10-2006 | REAL SOCIEDAD | 0 | VILLARREAL | 1 |
| Jornada 9 | 05-11-2006 | VILLARREAL | 3 | BETIS | 2 |
| Jornada 10 | 12-11-2006 | ATLETICO MADRID | 3 | VILLARREAL | 1 |
| Jornada 11 | 19-11-2006 | VILLARREAL | 1 | GETAFE | 0 |
| Jornada 12 | 26-11-2006 | FC BARCELONA | 4 | VILLARREAL | 0 |
| Jornada 13 | 03-12-2006 | VILLARREAL | 2 | GIMNASTIC | 0 |
| Jornada 14 | 10-12-2006 | CELTA | 1 | VILLARREAL | 1 |
| Jornada 15 | 17-12-2006 | VILLARREAL | 1 | OSASUNA | 4 |
| Jornada 16 | 20-12-2006 | RAC.SANTANDER | 2 | VILLARREAL | 1 |
| Jornada 17 | 07-01-2007 | VILLARREAL | 0 | VALENCIA | 1 |
| Jornada 18 | 14-01-2007 | ATHLETIC BILBAO | 0 | VILLARREAL | 1 |
| Jornada 19 | 21-01-2007 | VILLARREAL | 0 | SEVILLA | 0 |
| Jornada 20 | 28-01-2007 | VILLARREAL | 1 | REAL MADRID | 0 |
| Jornada 21 | 04-02-2007 | RECREATIVO | 2 | VILLARREAL | 1 |
| Jornada 22 | 11-02-2007 | VILLARREAL | 0 | DEPORTIVO | 2 |
| Jornada 23 | 18-02-2007 | ZARAGOZA | 1 | VILLARREAL | 0 |
| Jornada 24 | 25-02-2007 | VILLARREAL | 2 | MALLORCA | 1 |
| Jornada 25 | 04-03-2007 | ESPANYOL | 1 | VILLARREAL | 1 |
| Jornada 26 | 11-03-2007 | LEVANTE | 0 | VILLARREAL | 2 |
| Jornada 27 | 18-03-2007 | VILLARREAL | 1 | REAL SOCIEDAD | 1 |
| Jornada 28 | 01-04-2007 | BETIS | 3 | VILLARREAL | 3 |
| Jornada 29 | 08-04-2007 | VILLARREAL | 0 | ATLETICO MADRID | 1 |
| Jornada 30 | 15-04-2007 | GETAFE | 3 | VILLARREAL | 0 |
| Jornada 31 | 22-04-2007 | VILLARREAL | 2 | FC BARCELONA | 0 |
| Jornada 32 | 29-04-2007 | GIMNASTIC | 0 | VILLARREAL | 3 |
| Jornada 33 | 06-05-2007 | VILLARREAL | 1 | CELTA | 0 |
| Jornada 34 | 13-05-2007 | OSASUNA | 1 | VILLARREAL | 4 |
| Jornada 35 | 20-05-2007 | VILLARREAL | 2 | RAC.SANTANDER | 1 |
| Jornada 36 | 27-05-2007 | VALENCIA | 2 | VILLARREAL | 3 |
| Jornada 37 | 10-06-2007 | VILLARREAL | 3 | ATHLETIC BILBAO | 1 |
| Jornada 38 | 17-06-2007 | SEVILLA | 0 | VILLARREAL | 1 |