| Jornada 1 | 26-08-2007 | VALENCIA | 0 | VILLARREAL | 3 |
| Jornada 2 | 02-09-2007 | VILLARREAL | 0 | REAL MADRID | 5 |
| Jornada 3 | 16-09-2007 | MALLORCA | 0 | VILLARREAL | 1 |
| Jornada 4 | 23-09-2007 | VILLARREAL | 2 | MURCIA | 0 |
| Jornada 5 | 26-09-2007 | RAC.SANTANDER | 0 | VILLARREAL | 2 |
| Jornada 6 | 30-09-2007 | VILLARREAL | 1 | ATHLETIC BILBAO | 0 |
| Jornada 7 | 07-10-2007 | OSASUNA | 3 | VILLARREAL | 2 |
| Jornada 8 | 21-10-2007 | VILLARREAL | 3 | FC BARCELONA | 1 |
| Jornada 9 | 28-10-2007 | ZARAGOZA | 4 | VILLARREAL | 1 |
| Jornada 10 | 31-10-2007 | VILLARREAL | 3 | LEVANTE | 0 |
| Jornada 11 | 04-11-2007 | ATLETICO MADRID | 3 | VILLARREAL | 4 |
| Jornada 12 | 11-11-2007 | VILLARREAL | 3 | SEVILLA | 2 |
| Jornada 13 | 25-11-2007 | VILLARREAL | 1 | ALMERIA | 1 |
| Jornada 14 | 02-12-2007 | VALLADOLID | 2 | VILLARREAL | 0 |
| Jornada 15 | 09-12-2007 | VILLARREAL | 0 | BETIS | 1 |
| Jornada 16 | 16-12-2007 | GETAFE | 1 | VILLARREAL | 3 |
| Jornada 17 | 23-12-2007 | VILLARREAL | 1 | RECREATIVO | 1 |
| Jornada 18 | 06-01-2008 | ESPANYOL | 3 | VILLARREAL | 0 |
| Jornada 19 | 13-01-2008 | VILLARREAL | 4 | DEPORTIVO | 3 |
| Jornada 20 | 20-01-2008 | VILLARREAL | 3 | VALENCIA | 0 |
| Jornada 21 | 27-01-2008 | REAL MADRID | 3 | VILLARREAL | 2 |
| Jornada 22 | 03-02-2008 | VILLARREAL | 1 | MALLORCA | 1 |
| Jornada 23 | 10-02-2008 | MURCIA | 0 | VILLARREAL | 1 |
| Jornada 24 | 17-02-2008 | VILLARREAL | 0 | RAC.SANTANDER | 0 |
| Jornada 25 | 24-02-2008 | ATHLETIC BILBAO | 1 | VILLARREAL | 2 |
| Jornada 26 | 02-03-2008 | VILLARREAL | 0 | OSASUNA | 0 |
| Jornada 27 | 09-03-2008 | FC BARCELONA | 1 | VILLARREAL | 2 |
| Jornada 28 | 16-03-2008 | VILLARREAL | 2 | ZARAGOZA | 0 |
| Jornada 29 | 23-03-2008 | LEVANTE | 1 | VILLARREAL | 2 |
| Jornada 30 | 30-03-2008 | VILLARREAL | 3 | ATLETICO MADRID | 0 |
| Jornada 31 | 06-04-2008 | SEVILLA | 2 | VILLARREAL | 0 |
| Jornada 32 | 13-04-2008 | ALMERIA | 1 | VILLARREAL | 0 |
| Jornada 33 | 20-04-2008 | VILLARREAL | 2 | VALLADOLID | 0 |
| Jornada 34 | 27-04-2008 | BETIS | 0 | VILLARREAL | 1 |
| Jornada 35 | 04-05-2008 | VILLARREAL | 2 | GETAFE | 0 |
| Jornada 36 | 07-05-2008 | RECREATIVO | 0 | VILLARREAL | 2 |
| Jornada 37 | 11-05-2008 | VILLARREAL | 2 | ESPANYOL | 0 |
| Jornada 38 | 18-05-2008 | DEPORTIVO | 0 | VILLARREAL | 2 |